AKASAKA Takeshi

Affiliation
University of Tsukuba
Official title
Professor Emeritus
URL
Email
Iv"v*v"v:IE+v)vC+*,",wvCvxC!'
Research fields
Organic chemistry
Functional solid state chemistry
Research keywords
フラーレン
金属内包フラーレン
カーボンナノチューブ
化学修飾
機能性物質の創製
Research projects
Chemistry of Organic Heteroatom Compounds -- (current)/
Chemistry of Photooxygenation -- (current)/
Chemical Derivatization of Fullerenes and Metallofullerenes -- (current)/
組織化常磁性フラーレンの機能開拓　　　　　　　　　　　　　　　　　　　　　　　　2012 -- 2014Japan Society of for the Promotion of Science/基盤研究(B)6,890,000Yen
π空間に閉じこめられた物質系の創製と機能2008 -- 2012Ministry of Education, Culture, Sports, Science and Technology, Japan/新学術領域研究55,120,000Yen
高次π空間の創発と機能開発2008 -- 2012Ministry of Education, Culture, Sports, Science and Technology, Japan/新学術領域研究59,670,000Yen
組織化常磁性フラーレンの創製と機能2008 -- 2011Japan Society of for the Promotion of Science/基盤研究(A)47,710,000Yen
Ｍｉｓｓｉｎｇ　Ｍｅｔａｌｌｏｆｕｌｌｅｒｅｎｅの探索　　　　　　　　　　　　　2008 -- 2009Ministry of Education, Culture, Sports, Science and Technology, Japan/特定領域研究1,700,000Yen
常磁性フラーレン／典型元素間の相乗的協同効果による機能発現　　　　　　　　　　　2008 -- 2009Ministry of Education, Culture, Sports, Science and Technology, Japan/特定領域研究2,200,000Yen
フラーレンを鍵分子とするケイ素/炭素複合系の構築と機能2000 -- 2002Japan Society of for the Promotion of Science/基盤研究(A)8,800,000Yen
more...
Career history
1974-07 -- 1979-11筑波大学化学系技官
1979-12 -- 1981-05米国ブルックヘブン国立研究所博士研究員
1981-06 -- 1987-01筑波大学化学系講師
1987-02 -- 1996-03筑波大学化学系助教授
1996-04 -- 2000-12新潟大学大学院自然科学研究科教授
1999-04 -- 2001-03岡崎国立共同研究機構分子科学研究所客員教授
2001-01 -- 2004-03筑波大学先端学際領域研究センター／化学系教授
2004-04 -- 2013-03筑波大学先端学際領域研究センター／大学院数理物質科学研究科教授
2005-10 -- 2009-10中国西安交通大学客員教授
2008-09 -- 2012-09中国南京理工大学客員教授
more...
Academic background
1971-04 -- 1973-03名古屋工業大学 工学研究科 繊維高分子工学専攻
1974-04 -- 1975-06東京教育大学 Graduate School, Division of Natural Science 化学
Degree
1979-10理学博士University of Tsukuba
Academic societies
1980 -- (current)American Chemical Society
-- 2013Electrochemical Society
-- 2013The Society of Silicon Chemistry, Japan
-- (current)The Fullerene and NanoTtube Research Society
2010 -- (current)The Society of Physical Organic Chemistry, Japan
-- 2013近畿化学工業会
-- 2013THE JAPANESE PHOTOCEHMISTRY ASSOCIATION
-- (current)Chemical Society of Japan
-- 2013THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY
Honors & Awards
2014-03日本化学会賞
2011-04-11The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology: Prizes for Science and Technology (Research Category)
2008-09Award of The Yong Hae Kim Lectureship in KAIST
2003-04ITE Research Award
2001-03The Divisional Award of the Chemical Society of Japan for 2000
2000-11新潟日報文化賞
Articles
  • Experimental and Theoretical Studies of the Scandium Carbide Endohedral Metallofullerene Sc2C2@C82 and Its Carbene Derivative
    Y. Iiduka; T. Wakahara; K. Nakajima; T. Nakahodo; T. Tsu...
    Angew. Chem., Int. Ed./46/p.5562-5564, 2007-01
  • Isolation and Characterization of a Carbene Derivative of La@C82
    Y. Maeda; Y. Matsunaga; T. Wakahara; S. Takahashi; T. Tsuchiy...
    J. Am. Chem. Soc/126(22)/p.6858-6859, 2004-01
  • Oxidation of Phosphazine by Singlet Oxygen. High-Filed 31PNMR Spectroscopic Studies of 3-Phospha-1,2-dioxa-4,5-diazine and Phospha-1,2-dioxetane
    赤阪 健
    Journal of American Chemical Society/107/p.5539, 1985-01
  • Reaction of Singlet Oxygen with Sulfide : A Similarity of Singlet Oxygenation and Coupling Reaction of Cation Radical and Superoxide Ion
    赤阪 健
    Tetrahedron Letters/26/p.5049, 1985-01
  • Reaction of Singlet Oxygen with Indanone Phosphazine : Formation of Ketone and Lactone
    赤阪 健
    Tetrahedron Letters/26/p.843, 1985-01
  • Quenching of Singlet Oxygen by 4-(N, N-dimethylhydrazono-ethylidene)-2,6-diphenyl-4H-pyran
    赤阪 健
    Journal of Organic Chemistry/51/p.4477, 1986-01
  • Singlet Oxygen and Triazolinedione Addition to Azines
    赤阪 健
    Tetrahedron/42/p.5273, 1986-01
  • Reaction of Singlet Oxygen with 2-Pyrazoline : Implication for Cation Radical-Superoxide Ion Pair Intermediate
    赤阪 健
    Tetrahedron/42/p.3807, 1986-01
  • Reaction of singlet Oxygen with Thiirane : Iplication for a Spirodioxathiirane Intermediate
    赤阪 健
    Tetrahedron Letters/27/p.4473, 1986-01
  • Charge-transfer Photooxygenation of Sulfiddes in a Cryogenic Oxygen Matrix : IR Spectroscopic Observation of Persulfoxides
    赤阪 健
    Journal of American Chemical Society/109/p.8085, 1987-01
  • Stereospecific Oxygenation of 3-Adamantylidenetricyclo [3.2.1.02,4]octane : Singlet Oxygen vs. Electron-transfer Oxygenations
    赤阪 健
    Journal of American Chemical Society/109/p.1260, 1987-01
  • Generation of Singlet Diatomic Sulfur from 9,10-epidithio-9,10-dihydroantracene
    赤阪 健
    Tetrahedron Letters/28/p.6653, 1987-01
  • Reaction of singlet Oxygen with α, β-Unsaturated Aldimines
    赤阪 健
    Tetrahedron Letters/28/p.6633, 1987-01
  • Reaction of Singlet Oxygen with Methylenecyclopropanes : Formation of 4-Methylene-1,2-dioxolanes
    赤阪 健
    Tetrahedron Letters/28/p.217, 1987-01
  • Stereochemical Investigation of Photoepoxidation of Dioxetane-forming Olefins in the Presence of Sulfur Dioxide
    赤阪 健
    Chemistry Letters/p.335, 1987-01
  • Reaction of Dimesitylsilylene in a Cryogenic Oxygen Matrix : IR Spectroscopic Observation of a Silylene-Oxygen Adduct
    赤阪 健
    Journal of American Chemical Society/110/p.6270, 1988-01
  • Reaction of Singlet Oxygen with Thiirane : Peroxysulfenic Acid as a New Oxidizing Speciesn
    赤阪 健
    Journal of American Chemical Society/110/p.494, 1988-01
  • 3-Azacyclopropanespiro-1,2-dioxetane in Singlet Oxygenation of Methyleneaziridine
    赤阪 健
    Journal of Organic Chemistry/53/p.1670, 1988-01
  • Photochemical formation of Peroxidic Intermediates and Their Structures in a Cryogenic Oxygen Matrix
    赤阪 健
    日本化学会誌/p.1440, 1989-01
  • Singlet Oxygen and Triazolinedione Additions to α, β-Unsaturated Sulfoxides
    赤阪 健
    Tetrahedron/45/p.6657, 1989-01
  • Theoretical Study of a Silylene-Oxygen Adduct. Is a Silanone Oxide Structure (H2SiOO) Kinetically Stable in the Singlet State?
    赤阪 健
    Chemical Physics Letters/163/p.23, 1989-01
  • Formation of 1,2-Dioxolane in the Singlet Oxygenation of a Silicon-silicon α-Bond : Peroxonium Ion Intermediate
    赤阪 健
    Tetrahedron Letters/30/p.6705, 1989-01
  • A 3-Methylene-1,2-Dioxetane as a Possible Chemiluminescent Intermediate in Singlet Oxygenation of Allene
    赤阪 健
    Bulletein of Chemical Society of Japan/62/p.1367, 1989-01
  • Reaction of Singlet Oxygen with α, β-Unsaturated Aldimines : New Formation of 3-Amino-4-methylene-1,2-dioxolanes
    赤阪 健
    Heterocycles/28/p.445, 1989-01
  • Spectroscopic Studies on Charge-transfer Photooxygenation of Disiliranes
    赤阪 健
    Journal of American Chemical Society/112/p.7804, 1990-01
  • more...
Books
  • Chemical Derivatization of Fullerenes with Organosilicon Compounds
    赤阪 健
    1994-01
  • Structure and Reactivity of Endohedral Metallofullerenes
    赤阪 健
    1995-01
  • The Electronics Properties and Reactivities of Metallofullerenes
    赤阪 健
    1995-01
  • Unique Reducing Environment Inside Fullerene Cages
    赤阪 健
    1997-01
  • Cage Structures and Metal Positions of Endohedral Metallofullerenes
    赤阪 健
    1997-01
  • Chemical Derivatization of Fullerenes with Organosilicon Compounds
    赤阪 健
    1997-01
  • Novel-Fullerene-Based Organosilicon Compouuds
    赤阪 健
    1997-01
  • Isolation and Characterization of La2@C80 Isomers.
    赤阪 健
    1997-01
  • Determination of the Cage Structure of La@C82
    赤阪 健
    1998-01
  • Endohedrally Metal-deped Heterofullerenes
    赤阪 健
    1998-01
  • 「フラーレン化学の最前線 : 金属内包フラーレン」
    赤阪 健
    2000-01
  • 金属内包フラーレン化学の最前線－常磁性から反磁性へ－
    若原孝次; 赤阪 健; 小林 郁; 永瀬 茂
    化学, 2001-01
  • フラーレンの酸化ーその新しい展開
    新野康幸; 若原孝次; 赤阪 健
    オレオサイエンス, 2001-01
  • Endofullerenes: A New Family of Carbon Clusters
    T. Akasaka; S. Nagase
    Kluwer, Dordrecht, 2002-01
  • 単層カーボンナノチューブの高分散化
    前田 優; 若原孝次; 赤阪 健
    月刊MATERIALSTAGE, 2005-01
  • 金属内包フラーレンの構造解析ー最近の話題と進展
    赤阪 健・永瀬　茂
    化学, 2005-01
  • 金属内包フラーレンSc3C82の構造
    赤阪 健・永瀬　茂
    固体物理, 2005-01
  • 金属内包フラーレンの化学修飾
    若原孝次; 赤阪 健; 永瀬 茂
    現代化学、東京化学同人, 2006-05
  • 金属内包フラーレンの構造
    赤阪 健・永瀬　茂
    日本結晶学会誌, 2006-01
  • 金属内包フラーレンの分子変換
    土屋敬広・赤阪 健・永瀬　茂; +赤阪 健
    ナノカーボンハンドブック、（株）エヌ・ティー・エス, 2007-01
  • 単層カーボンナノチューブの化学修飾と分散化
    前田 優; 長谷川 正; 赤阪 健; 永瀬 茂
    ナノカーボンハンドブック、（株）エヌ・ティー・エス, 2007-01
  • 金属性単層カーボンナノチューブの分離法の開拓
    前田 優; 長谷川 正; 赤阪 健; 永瀬 茂
    ケミカルエンジニアリング、化学工業社, 2008-05
  • 新規フラーレン、カーボンナノチューブ系機能性材料の基礎研究
    土屋 敬広; 前田 優; 赤阪 健; 永瀬 茂
    触媒, 2009-01
  • 金属内包フラーレンの分子変換
    赤阪 健; 土屋敬広; 永瀬 茂
    Organometallic News, 2009-01
  • Construction of Supramolecular System Based on Endohedral Metallofullerenes
    Takahiro Tsuchiya; Takeshi Akasaka; Shigeru Nagase
    Bull. Chem. Soc. Jpn., 2009-02
  • more...
Teaching
2012-04 -- 2012-11Advanced Material ChemistryUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Experiments in Material Chemistry VUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Experiments in Material Chemistry IVUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Experiments in Material Chemistry IIIUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Experiments in Material Chemistry IIUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Experiments in Material Chemistry IUniversity of Tsukuba.
2012-04 -- 2013-03Seminar in Material Chemistry IIUniversity of Tsukuba.
2012-04 -- 2013-03Seminar in Material Chemistry IUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Exercise Chemistry IIIUniversity of Tsukuba.
2012-04 -- 2013-03Advanced Exercise Chemistry IIUniversity of Tsukuba.
more...
Talks
  • New Vistas in Chemistry of Nanocarbons: Organic Nanomaterials Based on Endohedral Metallofullerenes
    Takeshi Akasaka
    Forum for Nano-Materials Science 2012/2012-01-14
  • New Vistas in Chemistry of Fullerenes: Organic Nanomaterials based on Endohedral Metallofullerenes
    Takeshi Akasaka; Shigeru Nagase
    43rd IUPAC World Chemistry Congress/2011-07-30
  • New Vistas in Chemistry of Synthetic Carbon Allotopes: Organic Nanomaterials based on Endohedral Metallofullerenes
    Takeshi Akasaka; Shigeru Nagase
    The First Symposium on “Carbon Nanoforms” at Nanoscience, Nanotechnology and Molecular Materials Institute (INAMOL-UCLM)/2011-06-02
  • Creation of Cage-like Carbon π-Electron Molecules with Novel Structures and Properties: New Vistas in Fullerene Endohedrals
    赤阪 健
    大阪大学産業科学研究所セミナー/2010-06-24
  • フラーレンを鍵物質とする高次π空間の創発と機能開拓
    赤阪 健
    第21回基礎有機化学討論会/2010-09-09
  • Organic Nanomaterials based on Endohedral Metallofullerenes
    赤阪 健
    H22年度日本化学会関東支部群馬地区地域懇談会/2010-11-22
  • New Vistas in Fullerene Worlds: Endohedral Metallofullerenes
    Takeshi Akasaka
    International Symposium: The Chemistry of Synthetic Carbon Allotropes/2010-11-25
  • New Vistas in Endohedral Metallofullerenes
    Takeshi Akasaka; Shigeru Nagase
    Fullerene Silver Anniversary Symposium - FSAS 2010/2010-10-04
  • Creation of Cage-like Carbon pi-Electron Molecules with Novel Structures and Properties: New Vistas in Fullerene Endohedrals
    T. Akasaka
    The commemorative lecture for the accession to Adjunct Professor of Heilongjiang University/2010-02-12
  • New Vistas in Fullerene Endohedrals: Functionalization with Compounds from Main Group Elements
    T. Akasaka
    9th International Conference on Heteroatom Chemistry (ICHAC-9)/2009-06-30
  • In-depth Understanding of pi-Electron Systems: New Vistas in Fullerene Endohedrals
    T. Akasaka
    13th International Symposium on Novel Aromatic Compounds (ISNA-13)/2009-07-19
  • In-depth Understanding of pi-Electron Systems: New Vistas in Fullerene Endohedrals
    T. Akasaka
    Theoretical Organic Chemistry Workshop/2009-08-03
  • Emergence of Highly Elaborated pi-Space: Endohedral Metallofullerenes
    赤阪 健
    College of Chemistry and Molecular Engineering, Peking University/2009-03-23
  • New Fullerene World Opened by Functionalization with Main Group Element Compounds
    赤阪 健
    Academy of Jana Dlugosza/2008-11-28
  • New Fullerene World Opened by Functionalization with Main Group Element Compounds
    赤阪 健
    Polish Academy of Sciences/2008-11-27
  • New Fullerene World Opened by Functionalization with Main Group Element Compounds
    赤阪 健
    Wroclaw University of Technology/2008-11-26
  • New Fullerene World Opened by Functionalization with Main Group Element Compounds
    赤阪 健
    University of Lodz/2008-11-24
  • New Progress in Nanocarbon Science: Endohedral Metallofullerene
    赤阪 健
    Faculty of Chemical Engineering, Nanjing University of Science and Technology/2008-09-08
  • New Progress in Nanocarbon Science: Endohedral Metallofullerene
    赤阪 健
    The Yong Hae Kim Lectureship, Korean Institute of Science and Technology/2008-09-03
  • A New Approach for Nano-Device Applications - More is Different in Metallofullerenes
    赤阪 健
    NIMS Week 2008/2008-07-15
  • New Progress in Chemistry of Nanocarbons: Endohedral Metallofullerenes
    赤阪 健
    Institute of Nanoscience and Nanotechnology for Molecular Materials, University of Castilla - La Mancha/2008-06-13
  • New Progress in Chemistry of Nanocarbons: Endohedral Metallofullerenes
    赤阪 健
    Department of Chemistry and Institute for Nanoscience, Autonoma University at Madrid/2008-06-10
  • New Progress in Chemistry of Nanocarbons: Endohedral Metallofullerenes
    赤阪 健
    Department of Chemistry, University of Compultense at Madrid/2008-06-09
  • New Progress in Chemistry of Nanocarbons: Endohedral Metallofullerenes
    赤阪 健
    Department of Chemistry, University of California at Davis/2008-07-01
  • 高次π空間の創発
    赤阪 健
    日本化学会第89回春季年会/2009-03-27
Professional activities
2011 -- 2014The Society of Physical Organic Chemistry, Japan理事
2011 -- 2012近畿化学工業会代議員
2011 -- 2011Chemical Society of Japan関東支部長

(Last updated: 2024-07-30)